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1 article(s) from Clements, Philip

β-Cyclodextrin- and adamantyl-substituted poly(acrylate) self-assembling aqueous networks designed for controlled complexation and release of small molecules

Liang Yan,
Duc-Truc Pham,
Philip Clements,
Stephen F. Lincoln,
Jie Wang,
Xuhong Guo and
Christopher J. Easton

Beilstein J. Org. Chem. 2017, 13, 1879–1892, doi:10.3762/bjoc.13.183

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Graphical Abstract

Figure 1: β-Cyclodextrin- and adamantyl-substituted poly(acrylate)s PAAβ-CDen, PAAADen, PAAADhn, and PAAADddn...

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Figure 2: ITC data for the PAAβ-CDen/PAAADen, system obtained in aqueous Na₂HPO₄/KH₂PO₄ pH 7.0 buffer at I = ...

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Figure 3: ITC data for the PAAβ-CDen/PAAADddn system obtained in aqueous Na₂HPO₄/KH₂PO₄ pH 7.0 buffer at I = ...

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Figure 4: Representation of ditopic complexation of an ADddn substituent of PAAADddn, by two β-CDen substitue...

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Figure 5: 2D NOESY ¹H NMR spectrum of 0.44 wt % PAAβ-CDen ([β-CDen] = 2.0 × 10⁻³ mol dm⁻³) and 0.60 wt % PAAA...

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Figure 6: (a) Molar absorbance variation of 1.5 cm³ of a EO solution ([EO] = 2.00 × 10⁻⁵ mol dm⁻³) with 20 se...

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Figure 7: (a) Molar absorbance variation of 1.5 cm³ of a EO solution ([EO] = 2.00 × 10⁻⁵ mol dm⁻³) with 20 se...

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Figure 8: Speciation plot with [β-CDen]_total = 100% for the PAAβ-CDen/PAAADhn/EO system.

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Figure 9: 2D NOESY ¹H NMR spectrum of MR ([MR] = 2.0 × 10⁻³ mol dm⁻³) in solution with PAAβ-CDen (0.78 wt %, ...

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Figure 10: Viscosity variations at a 0.03 s⁻¹ shear rate of 1.14 wt % PAAβ-CDen/PAAADen, 1.18 wt % PAAβ-CDen/P...

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Figure 11: Representation of dye complexation in the PAAβ-CDen/PAAADen and PAAβ-CDen/PAAADhn networks.

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Figure 12: Release profiles for EO (i), MO (ii) and MR (iii) from aqueous (a) Na₂HPO₄/KH₂PO₄ buffer alone, (b)...

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Published 07 Sep 2017

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